Polymers Textiles

Advances in Controlled/Living Radical Polymerization by Krzysztof Matyjaszewski

By Krzysztof Matyjaszewski

Offers new advancements in controlled/living radical polymerization in 3 components: atom move radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation move (RAFT). additionally contains synthesis and characterization of many new materials.

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Tsujii, Y . ; Davis, T. , Eds. John Wiley & Sons, New York, N Y , 2002; Chapter 9, p 407. ; Tsujii, Y. ; ACS Symp. Ser. 768; American Chemical Society: Washington, DC, 2000; p 27. ; Fukuda, T. Macromolecules 1998, 31, 2809. ; Fukuda, T. Macromolecules 2002,35 , 5801. ; Fukuda, T. Macromolecules2003,36(4), in press. ; Thang, S. H. Macromolecules 2001,34 , 402. ; Quinn, J. ; Morsley, D. ; Davis, T. P. J. Polym. Sci. : Polym. 2001,39, 1353. Monteiro, M . ; de Brouwer, H. Macromolecules 2001, 34, 349.

Upon increasing X, this results in a relative enhancement of the D A content of the monomer mixture and thus in an enhancement of copolymerization Ap. As a consequence, lk is lowered toward increasing ^ when data are plotted for the same initial monomer mixture composition, /MMA┬░- In the (intra-family) M A - D A copolymerization, TMA stays close to fuA during the entire course of a polymerization up to high conversion (6). The /k values of M M A - r i c h and DA-rich systems are very different at low X, but approach each other at high degrees of monomer conversion.

ACS Symp. Ser. 2000, 768, 108. ; Fukuda, T. Macromolecules 2002, 353, 5081. ; Tsujii, Y . ACS Symp. Ser. This Volume. (a) Ananchenko, G . ; Fischer, H . J. Polym. Sci. : Polym. Chem. 2001, 39, 3604. (b) Ananchenko, G . ; Fischer, H . ; Tordo, P. J. Polym. Sci. : Polym. Chem. 2002, 40, 3264, and references therein. 1, The MathWorks Inc. 2001. , PhD Thesis University of Marseille III, 2002. ; Macromol. Chem. Phys. 2000, 201, 2138. From simulations of data kindly provided by D. Bertin and O. Guerret, Marseille.

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